Tris[2-(2-pyridylsulfanyl)ethyl]ammonium perchlorate
نویسندگان
چکیده
In the title molecular salt, C(21)H(25)N(4)S(3) (+)·ClO(4) (-), an intra-molecular N-H⋯N hydrogen bond stabilizes the conformation of the cation. The three N-C-C-S torsion angles are 91.7 (2), 100.9 (2) and 167.02 (14)°.
منابع مشابه
Bis[2-(2-pyridylsulfanyl)ethyl]ammonium perchlorate
The cation and anion of the title salt, C(14)H(18)N(3)S(2) (+)·ClO(4) (-), lie on a twofold rotation axis. The cation is a W-shaped entity with the aromatic rings at the ends; the ammonium NH(2) (+) group is a hydrogen-bond donor to the pyridyl N atoms. The perchlorate ion has one O atom disordered over two sites in a 0.50:0.50 ratio.
متن کامل{Tris[2-(imidazol-2-ylmethylimino)ethyl]methylammonium}iron(II) tris(perchlorate) dihydrate
The title complex, [Fe(C(19)H(27)N(10))](ClO(4))(3)·2H(2)O, is a new polymorph of an iron(II) Schiff base complex of tris-(2-amino-ethyl)methyl-ammonium with imidazole-2-carboxaldehyde. The octa-hedral Fe(II) atom is bound to three facial imidazole N atoms with average Fe-N(imidazole) and Fe-N(imine) bond distances of 1.963 (5) and 1.951 (5) Å, respectively. The central N atom of the tripodal l...
متن کاملTris(μ2-methanolato)-μ3-oxido-tris{[(E)-4-chloro-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato]manganese(III)} perchlorate–dichloromethane–diethyl ether (1/1.1/0.9)
In the title compound, [Mn3(C14H12ClN2O)3(CH3O)3O]ClO4·1.1CH2Cl2·0.9C4H10O, the cation consists of a central Mn3O core with μ2-methano-late bridging between adjacent MnIII atoms, thus giving each MnIII atom a mer-O3 coordination environment. Six-coordination for each MnIII atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)phenolate. ...
متن کاملPoly[[bis{μ3-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)]
In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra-zole N(4) atoms of six symmetry-equivalent tris-[2-(1H-tetra-zol-1-yl)eth-yl]amine ligands (t(3)z) in the form of a Jahn-Teller-distorted octa-hedron with Cu-N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereoc...
متن کاملTris[2-(2-thienylmethylamino)ethyl]ammonium triiodide
In the title compound, C(21)H(33)N(4)S(3) (3+)·3I(-), three secondary amines are protonated, while the central amine remains unprotonated. One thio-phene is disordered with an occupancy ratio of 0.868 (6)/0.132 (6). Each protonated amine is involved in N-H⋯I hydrogen-bonding inter-actions with the iodide anions.
متن کامل